Silicon Dioxide SiO2 Silica

  • Main glass-former in ceramics
  • Sometimes comprises 50-75% total oxides in glaze
  • Has melting point of 3110°F
  • Usually non-toxic when combined in melt with other minerals
  • As “free silica” dust it can cause silicosis, an untreateable lung disease
  • Presence increases hardness, durability and acid resistance
  • Has very little effect on color
    • If too much is added it will create silica mattes, opaque, sugary surfaces that will affect color because much of the material in glaze remains unmelted
  • Generally added to glazes in its 200-mesh form
    • Available in other mesh sizes, too
  • Has over 20 different structures, or crystal formations, which only three most directly pertain to ceramics
  • Can exist as a crystal glass, or cristobalite
    • All of these materials are chemically the same
    • Only physical arrangement is different
  • As crystal, it has a very ordered arrangement
    • With high rate of expansion and contraction
  • Cristobalite
    • Crystalline state of silica
    • Even higher expansion and contraction rate than crystal silica
    • As glass, it has cooled so quickly it has amorphous arrangement
    • Very low expansion and contraction rate
    • Has medium surface tension and viscosity.
  • Insoluble sources include silica (various mesh sizes), cristobalite, flint/chert (containing up to 5% CaO), Kaolin/clay, feldspar, wollastonite, talc, Frits, zirconium silicate, Macaloid, pyrophyllite, silicon carbide, kyanite, wood ash (some plant ash contains up to 70% silica), sand, and mica.

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