Zinc Oxide ZnO

  • Toxic metal oxide
  • Usually used as an auxiliary flux in oxidizing atmospheres
  • Although it is an active flux, it has a high melting point of 3587°F
  • If fired in reduction it will change to metal zinc
    • Will volatilize at 1742°F
  • Industry used properties of zinc to flash-glaze bricks by placing zinc-filled containers through kiln and firing in reduction
  • Volatilized zinc falls from chimney to kiln yard and becomes toxic dust hazard
  • Zinc Oxides color response is dramatic, either good or bad
  • Can heighten colors with copper and cobalt but produce dull colors when combined with chrome
  • Gives strength and durability to glazes
  • Improves elasticity
  • May act as an opacifier
  • Used in larger amounts to produce crystalline effects
  • Has medium viscosity and surface tension, which make it somewhat prone to crawling, exacerbated by high initial shrinkage of raw zinc oxide during firing
  • Often calcined zinc oxide is used to reduce the initial shrinkage
  • Has low expansion and contraction rate, so it can reduce crazing
  • Keep in mind it can contain lead impurities
  • Insoluble sources are zinc oxide and calcined zinc oxide

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