Copper Oxide CuO, Cu2, Cu4O, and CuCO3

Copper oxide in a glass bowl
  • Very active flux
  • Disperses well in glaze
  • Although melts at 2098°F, another popular form, copper carb, melts at 932°F and changes to copper oxide
  • Copper can produce many colors like red, pink, green, blue, black and metallic lusters
  • Used alone it can produce reds in heavy reduction
    • with the addition of small amounts of tin oxide (.3%) or iron oxide, it’s even more effective in making reds.
  • In a sodium base, it will produce blues
  • In strike firing cycle it will produce metallic lusters
  • Extremely sensitive to oxidation or reduction firings
    • Because heated copper oxide molecule releases an oxygen atom fairly easily which is then transformed into a reduced state such as Cu2O or even copper metal (Cu)
  • Volatilizes at high temps
    • In this state, material is called fugitive copper
  • As it swirls throughout kiln the copper may be picked up by other pots, causing flashes of red or pink on them
    • Particularly ones that have tin oxide in the glaze
  • High expansion and contraction rate may cause glaze crazing
  • Disperses easily in glazes, producing uniform color
    • Black copper oxide
      • because of its course mesh size, causes speckling
    • Red copper oxide
      • strongest of all copper oxides
      • difficult to mix with water because it is coated to halt oxidation during storage
        • few drops of dish soap in glaze water will assist in dispersing red copper oxide
  • For substitution purposes
    • 113g copper sulfate=100g of carbonate=72g black = 64.7g of red oxide
  • Copper materials are available from most ceramic suppliers in several forms
    • copper carbonate (CuCO2) a green, 200-mesh powder
    • black copper oxide (CuO) 100-mesh
    • Red copper oxide (Cu2O)
      • available in 200 mesh,
    • though grades offered will vary by supplier
    • Can also obtain copper sulfate
      • water-soluble blue crystal that is used as agricultural poison
  • Copper materials are toxic and should be handled with care

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